CAS · 14264-16-5
Product Overview
Bis(triphenylphosphine)nickel(II)chloride is a high-purity catalysts-auxiliary-agent supplied for industrial and specialty chemical applications. Contact our team for specifications, packaging options and lead times.
Product Specifications
| Appearance: | Gray green to dark green solid |
|---|---|
| Assay (Element analysis): | 98% min |
| Ni: | 8.9% min |
| C: | 66.09 |
| H: | 4.62 |
| Solvent: | 0.5% max |
Applications
Bis(triphenylphosphine)nickel(II) chloride is primarily employed as a homogeneous catalyst in organic synthesis. It is widely used in cross-coupling reactions such as Suzuki-Miyaura, Kumada, and Negishi couplings, facilitating the formation of carbon-carbon bonds between aryl, vinyl, or alkyl halides and organometallic reagents. In polymer chemistry, it acts as a catalyst for olefin polymerization and the synthesis of functionalized polymers. It is also applied in reductive and dehalogenation reactions, enabling selective transformations of halogenated organic substrates. Beyond laboratory-scale synthesis, it is utilized in research and development to study reaction mechanisms, develop new catalytic systems, and explore transition metal-mediated transformations in complex molecule synthesis.
Benefits
The benefits of bis(triphenylphosphine)nickel(II) chloride include its high catalytic efficiency, stability, and versatility. Its phosphine ligands stabilize the nickel center, allowing for controlled and selective catalytic activity under mild conditions. It provides high yields in carbon-carbon bond-forming reactions and supports a broad substrate scope, making it suitable for both simple and complex organic transformations. The compound is also relatively stable under ambient conditions and soluble in common organic solvents, which facilitates handling and reaction setup. Additionally, it enables fine-tuning of reactivity through ligand modification, allowing chemists to optimize reaction conditions for specific applications in synthesis and polymer chemistry.
Conclusion
In summary, bis(triphenylphosphine)nickel(II) chloride is a versatile nickel-phosphine coordination complex widely used as a homogeneous catalyst in cross-coupling, polymerization, and reductive reactions. Its high efficiency, stability, and ligand-controlled reactivity make it a valuable tool in organic and polymer chemistry. With its broad applicability and reliability, it supports both academic research and industrial synthesis of complex molecules, functional polymers, and advanced materials.
Previous
1,2,3,4,5-Pentaphenyl-1-(di-tert-butylphosphino)ferrocene丨CAS 312959-24-3
Next