CAS · 89827-45-2
Product Overview
4-Bromodibenzo[b,d]furan is a high-purity oled-materials supplied for industrial and specialty chemical applications. Contact our team for specifications, packaging options and lead times.
Product Specifications
| Appearance: | White powder |
|---|---|
| Purity (HPLC): | 99.5% min |
| MP: | 66.0~70.0℃ |
Applications
1. Organic Synthesis Intermediate
4-Bromodibenzo[b,d]furan is widely used as a building block in organic chemistry for:
Cross-coupling reactions:
The bromine substituent allows palladium-catalyzed cross-coupling (e.g., Suzuki, Stille, Negishi, Sonogashira) to attach various functional groups including aryl, alkynyl, and heterocyclic moieties.
Synthesis of π-conjugated systems:
The dibenzofuran core is important for constructing rigid, planar aromatic systems with extended conjugation, useful in optoelectronic applications.
2. Materials Science and Organic Electronics
Used as a key building block for:
Organic light-emitting diodes (OLEDs)
Organic semiconductors
Photovoltaic materials
The dibenzofuran moiety contributes thermal stability, high fluorescence, and efficient charge transport.
3. Pharmaceutical and Agrochemical Research
The dibenzofuran scaffold appears in bioactive molecules:
Acts as a core structure in various pharmaceutical candidates due to its planar, rigid architecture.
Used in the design of enzyme inhibitors, antimicrobials, and herbicides.
4. Fluorescent Probes and Sensors
The aromatic furan system combined with substitution patterns like bromine allows:
Development of fluorescent molecular probes
Construction of chemosensors for detecting metal ions and organic molecules
Benefits
1. Versatile Synthetic Handle
The bromine atom at the 4-position offers:
Regioselective reactivity in coupling reactions
Ability to precisely modify the molecule for targeted functionalization
2. Rigid and Planar Structure
The dibenzofuran core provides:
Excellent π-conjugation and planarity
High thermal and photostability, which are beneficial for materials performance
3. Useful Electronic Properties
Dibenzofuran derivatives have:
Strong fluorescence
Good charge mobility
Potential as hole-transport materials or hosts in optoelectronic devices
4. Chemical Stability
Compared to other heterocycles, dibenzofuran derivatives show better chemical and photochemical stability, prolonging device lifetimes in electronics.
Conclusion
4-Bromodibenzo[b,d]furan (CAS 89827-45-2) is an important intermediate in organic synthesis and materials chemistry. Its brominated dibenzofuran scaffold serves as a versatile building block for organic electronics, pharmaceutical research, and fluorescent probe development. The compound's combination of reactive halogen substitution, planar aromatic core, and thermal stability makes it ideal for applications requiring robust π-conjugated systems with tunable electronic and optical properties.
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