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Product Line: Electronic Chemicals

2-Bromo-7-chloro-9,9-dimethyl fluorene

CAS 605630-37-3

Molecular structure of 2-Bromo-7-chloro-9,9-dimethyl fluorene

CAS · 605630-37-3

01

Product Overview

2-Bromo-7-chloro-9,9-dimethyl fluorene is a high-purity oled-materials supplied for industrial and specialty chemical applications. Contact our team for specifications, packaging options and lead times.

02

Product Specifications

Appearance White powder
Purity(HPLC) 99% min
MP 157.0~161.0℃
03

Applications

 

 

1. OLED and Organic Semiconductor Materials

This compound is frequently used as an intermediate in the synthesis of functionalized fluorene derivatives for organic light-emitting diodes (OLEDs) and organic field-effect transistors (OFETs).

The dimethylfluorene core provides high thermal stability and good photophysical properties, while the halogen substituents allow for further cross-coupling reactions.

2. Suzuki and Stille Coupling Precursor

The bromine and chlorine atoms serve as reactive sites for palladium-catalyzed cross-coupling reactions, enabling the attachment of aryl, heteroaryl, or vinyl groups.

Suitable for constructing π-conjugated systems and donor–acceptor materials in optoelectronic devices.

3. Advanced Polymer Synthesis

A useful monomer for functional polymers such as conjugated polymers, which are applied in:

Photovoltaics

Sensors

Electroluminescent materials

The rigid fluorene framework contributes to high glass transition temperatures and excellent film-forming ability.

4. Material Science and Nanotechnology

Serves as a building block in the creation of nanostructured materials and fluorene-based dendrimers for molecular electronics or light-harvesting applications.

04

Benefits

 

 

✅ Versatile Functionalization

Dual halogenation (Br and Cl) allows for selective stepwise functionalization, enabling the synthesis of complex molecular architectures.

✅ Thermal and Photochemical Stability

The 9,9-dimethylfluorene skeleton imparts excellent thermal durability, essential for materials used in electronic devices.

✅ Optoelectronic Performance

Fluorene-based materials derived from this compound are known for high photoluminescence quantum yields, good charge mobility, and tunable emission wavelengths.

✅ Scaffold for Molecular Engineering

Enables development of donor–acceptor systems, push-pull chromophores, and π-conjugated systems for fine-tuning electronic properties in device applications.

05

Conclusion

2-Bromo-7-chloro-9,9-dimethylfluorene (CAS 605630-37-3) is a highly functional intermediate used in organic electronics, advanced materials, and synthetic chemistry. Its dual halogenation offers excellent versatility in cross-coupling reactions, while the fluorene core ensures structural rigidity, thermal stability, and strong optoelectronic performance. It is particularly valuable in the development of OLEDs, conjugated polymers, and functional organic materials.

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