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Product Line: Electronic Chemicals

1-(2-bromophenyl)naphthalene

CAS 18937-92-3

Molecular structure of 1-(2-bromophenyl)naphthalene

CAS · 18937-92-3

01

Product Overview

1-(2-bromophenyl)naphthalene is a high-purity oled-materials supplied for industrial and specialty chemical applications. Contact our team for specifications, packaging options and lead times.

02

Product Specifications

Appearance: White powder
Purity (HPLC): 99.5% min
MP: 97.0~101.0℃
03

Applications

 

 

1. Organic Electronics and Optoelectronic Materials

OLED Materials:

Acts as a precursor for hole-transport materials and host molecules due to its rigid and conjugated aromatic structure.

The extended π-system is beneficial for enhancing light emission efficiency and stability in organic light-emitting diodes.

Semiconducting Polymers:

Serves as a monomer or co-monomer for synthesizing conjugated polymers used in organic field-effect transistors (OFETs) and organic photovoltaics (OPVs).

2. Intermediate in Cross-Coupling Reactions

The ortho-bromine atom allows for palladium-catalyzed cross-coupling reactions such as:

Suzuki coupling

Stille coupling

Heck reactions

These make it a versatile intermediate for building more complex arylated or heteroarylated molecules.

3. Ligand and Scaffold in Coordination Chemistry

The planar biphenyl-like structure can be used to create ligand frameworks for transition metal complexes, useful in:

Homogeneous catalysis

Organometallic synthesis

Functional coordination materials

4. Fluorescent Materials and Sensors

The naphthalene moiety contributes to intrinsic fluorescence, making derivatives of 1-(2-bromophenyl)naphthalene potential candidates for:

Fluorescent dyes

Chemical and biological sensors

Light-harvesting systems

5. Research in Molecular Electronics

Used in the development of:

Molecular wires

Organic memory devices

Host–guest supramolecular systems

04

Benefits

 

1. Reactive Handle for Diversification

The bromo group allows for efficient downstream modifications, expanding the chemical space for molecular design.

2. Rigid, Planar Structure

Promotes π-π stacking, essential for efficient charge transport in organic semiconductors.

Improves film-forming properties for spin-coating and vapor deposition.

3. High Thermal Stability

Aromatic frameworks like naphthalene ensure good thermal and oxidative stability, which is critical in device performance.

4. Strong Conjugation

Provides excellent optical and electronic characteristics, such as high light absorption, tunable bandgaps, and strong fluorescence.

5. Versatile Precursor

Can be further functionalized into polycyclic aromatic hydrocarbons (PAHs), heterocycles, or dendritic structures used in nanotechnology and advanced materials.

05

Conclusion

1-(2-Bromophenyl)naphthalene (CAS 18937-92-3) is a versatile and valuable compound in advanced material synthesis, especially in the field of organic electronics, optoelectronics, and functional molecular design. Its combination of a reactive bromine substituent and a robust aromatic framework makes it ideal for use in cross-coupling chemistry, fluorescent material design, and semiconductor research. Its ability to be readily modified enables the creation of novel compounds with tailored photophysical and electronic properties.

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